GLITSIRRIZIN KISLOTASINING SIMOB(II) IONI BILAN METALLOKOMPLEKSI SINTEZI
Keywords:
Kalit so’zlar: Glitsirrizin kislota, sintez, metallokompleks, UB-, IQ- spektroskopiya.Abstract
Abstrakt: Ushbu ishda GK ning Hg(II) ioni bilan kompleksi olindi va olingan metallokompleksning fizik-kimyoviy va spektral xususiyatlari tahlil qilindi. Hg+2 va GK (1:2) kompleksining IQ-Fure-spektrlarida bir qator valent sohalarning dastlabki agentlar ko’rsatkichlariga nisbatan siljish holatlari qayd qilindi. -OH guruhiga tegishli valent tebranishlar qisman oldga 3374 sm–1 1708-1719 sm–1 C=O guruh oldinga siljidi. Shuningdek, kompleks tarkibida C=C bog’larning yutilishi sohalari 1648 sm–1 holatda guruhlarining yutilish sohasi qisman ortga siljigani qayd qilindi, bu o‘z navbatida ularning kimyoviy bog‘lar hosil qilishda qatnashishini ko‘rsatadi.
References
1. Cosmetic Ingredient Review Expert Panel. (2007). Final report on the safety assessment of glycyrrhetinic acid, potassium glycyrrhetinate, disodium succinoyl glycyrrhetinate, glyceryl glycyrrhetinate, glycyrrhetinyl stearate, stearyl glycyrrhetinate, glycyrrhizic acid, ammonium glycyrrhizate, dipotassium glycyrrhizate, disodium glycyrrhizate, trisodium glycyrrhizate, methyl glycyrrhizate, and potassium glycyrrhizinate. International journal of toxicology, 26, 79-112.
2. Gottschalck, T. E., & McEwen Jr, G. N. (2004). International Cosmetic Ingredient Dictionary and Handbook, 10th edn, Vol. 1. The Cosmetic Toiletry and Fragrance Association, 146.
3. Sohrabi, B., Mansouri, F., & Karimi, S. (2022). The natural non-ionic magnetic surfactants: nanomicellar and interfacial properties. Journal of Nanostructure in Chemistry, 1-14.
4. Abdurahmanova, K. U., Kushiev, H. K., & Iroda, M. J. (2021). Adsorption Properties of Monoammonium Salt of Glycyrrhizic Acid. Int. J. Curr. Microbiol. App. Sci, 10(04), 823-829.
5. Abdurakhmanova, U., & Kushiev, K. (2021). Sorption-spectrometric determination of nickel by monoammonium salt of glycirrizic acid. Chemistry and chemical engineering, 2021(1), 12.
6. Isaev, Yusup & Rustamov, Sanzhar & Askarov, Ibragim & Хожиматов, Махсадбек & Зайцев, Сергей. (2020). Synthesis of glycyrrizin acid derivatives and their classification by cn fea. Technovation. 2. 171-175.
7. Kong, Y., Chen, F., Su, Z., Qian, Y., Wang, F. X., Wang, X., ... & Liu, H. K. (2018). Bioactive ruthenium (II)-arene complexes containing modified 18β-glycyrrhetinic acid ligands. Journal of Inorganic Biochemistry, 182, 194-199.